Thursday 7 March 2013

Sustainable Development Aspects of the One Atmosphere Uniform Glow Discharge Plasma



OAUGDP was developed at the University of Tennessee. It is a non-thermal glow discharge that operates in air (and other gases) at room temperature and atmospheric pressure. My project is to research the OAUGDP and simulate an equivalent circuit of the glow plasma discharge with PSPICE. It is only a simulation of the discharge so it has no regulations except for copyright laws of the used published material and software for the research. Even if the discharge equivalent circuit is to be build there are no regulations other than the health/safety rules of the department’s laboratory as the OAUGDP is operated in air, without the use of vacuum, and at a voltage of 10V. Despite my thorough search for relevant regulations of OAUGDP the only regulation I could find was about high voltage operation - ISBN 978-0-626-21281-0, NRS 040-5:2007. Since industrial generation of glow discharge plasma involves the use of voltages in the scope of 1-10kV.

More economical and ecologically friendly technologies are sought today by representatives of many industrial sectors to meet new sustainable regulations and competitive pressure. Glow discharge plasma uses air as a working gas at an atmospheric pressure and room temperature - resource-efficient. The majority of industrial plasma processing is done with glow discharges at pressures below 10 torr. This tends to limit such applications to high-value items, as a result of the high capital cost of vacuum systems and the production constraints of batch processing.

Some of the advantages of the industrial use of OAUGDP technology are:

1.     Plasma methods can accomplish results more efficiently and cheaply than competing technologies
             -  Non-thermal and non-water cleansing, purification and sterilization

2.     Plasma can perform tasks that can be accomplished in no other way
             - Fluorescent lamp based on the OAUGDP, which requires neither a vacuum nor the use of mercury. Thin films are made only with plasma methods.

3.     Plasma processes usually accomplish results without producing large volumes of unwanted by-products or waste materials
             - Plasma has no emissions, does not require consumables to operate and it does not generate harmful by-products

4.     Plasma processes usually accomplish results without producing significant quantities of toxic wastes
             - OAUGDP generates ozone which dissolves in the air over a short period of time (1-2hrs)

The above characteristics of plasma and the glow discharge plasma in particular, have always been advantageous. They are becoming increasingly essential in the current, progressively stricter regulatory atmosphere, and in an international competitive environment in which the United Kingdom must rely on its advanced technological skills to compete economically with low-wage, lower-tech overseas competitors.

There are many prospective industrial applications of the OAUGDP which include subsonic plasma aerodynamic flow control; increasing the surface energy and wettability of fabrics, films, and solid surfaces; sterilizing medical equipment and air filters; stripping of photoresist and directional etching of possible microelectronic relevance; oxide coating on metals etc.
Furthermore, working with OAUGDP has the advantage of being an environmentally friendly process. This is due to its simplicity of application as a dry application media as well as its potential to cut down on usage of resources which include water, chemicals as well as energy. Not only it uses less energy but in Atlanta, USA the company Geoplasma uses it to blast garbage with a stream of plasma which vaporizes the trash into pressurized gas that spins a turbine to create electricity. That way fewer emissions are released than incineration and the volume of landfills reduced as well as power prices. The OAUGDP technology is supported by the U.S. Environmental Protection Administration (EPA). With their support and demand some applications of the glow discharge plasma have been commercialised such as the air filtration system that destroys all microorganisms developed by AGT® and the fluorescent lamp that requires neither mercury nor vacuum invented by the University of Tennessee Plasma Science Laboratory. 

With the rising number of sustainable regulations the One Atmosphere Uniform Glow Discharge Plasma comes as a solution for greener industrial works. The full potential has not yet been reached for this technology. I would like to further study the OAUGDP and explore what other capabilities it holds. My research could nd even more applications for this phenomenon of the 4th state of matter. New technologies can be implemented such as a device that reduces exhaust soot from vehicles and industrial chimneys or food sterilizer that cleanses the food without the use of heat or chemicals which will elongate its life. Another useful action would be to try promoting this technology to be integrated in more industrial businesses which would reduce pollution and waste.

Tuesday 5 March 2013

2nd group meeting (01.02.2013)

  We are still reading the materials on the project. We have decided to simulate the following circuit as an equivalence of the glow discharge. The Zener diodes represent the breakdown voltages which identify the Townsend discharge. The equivalent circuit for the glow discharge is:
     

Monday 4 March 2013

Reading Materials

There are not many materials particularly for our project but there are a lot on plasma. I manage to find over 20 journals and scientific reports holding information on low pressure, non-thermal plasmas but the most relevant ones to OAUGDP are:

  • PRINCIPLES OF PLASMA DISCHARGES by Michael A. Lieberman
  • Gas discharge plasmas and their applications byAnnemie Bogaerts, Erik Neyts, Renaat Gijbels, Joost van der Mullen
  • Plasma generation and plasma sources by H Conrads and M Schmidt
  • A uniform glow discharge plasma source at atmospheric pressure by Se Youn Moon, W. Choe, and B. K. Kang
  • PSpice Simulation of One Atmosphere Uniform Glow Discharge Plasma (OAUGDP) Reactor Systems by Zhiyu Chen
  • The One Atmosphere Uniform Glow Discharge Plasma (OAUGDP)—A Platform Technology for the 21st Century by J. Reece Roth, Life Fellow, IEEE, Sirous Nourgostar, Student Member, IEEE, and Truman A. Bonds, Student Member, IEEE
  • Plasma Physics by Dr. Philip D. Rack
  • Impedance Matching for One Atmosphere Uniform Glow Discharge Plasma (OAUGDP) Reactors by Zhiyu Chen
  • A One Atmosphere Uniform Glow Discharge Plasma (OAUGDP) reactor for plasma chemical vapor deposition (pcvd) of thin films by Zhiyu Chen and J. Reece Roth
  • Filamentary and Homogeneous Modes of Dielectric Barrier Discharge (DBD) in Air: Investigation through Plasma Characterization and Simulation of Surface Irradiation by Priyadarshini Rajasekaran, Philipp Mertmann, Nikita Bibinov, Dirk Wandke, Wolfgang Viol, Peter Awakowicz
  • Filamentary, Patterned, and Diffuse Barrier Discharges by Ulrich Kogelschatz
  • Physics and chemistry in a glow dielectric barrier discharge at atmospheric pressure: diagnostics and modelling by F. Massines, P. Se´gur, N. Gherardi, C. Khamphan, A. Ricard
  • Atmospheric pressure plasma deposition of thin films by Townsend dielectric barrier discharge by Francoise Massines , Nicolas Gherardi, Antonella Fornelli, Steve Martin
  • One atmosphere uniform glow discharge plasma, US Patent, inventors - John R. Roth, Peter Tsai, Chaoyu Liu, Mounir Laroussi, Paul Spence, all of Knoxville, Tenn
I have sent everything I had found to my teammates for reading.


1st group meeting (08.12.2012)

On the first meeting we were a bit confused about what our project is about - whether we need to build a circuit or just strictly read everything about OAUGDP and summarize it on few pages. Also we were looking for the suggested authors and their journals from the IEEE and the web, also all kinds of relative materials on the subject.

1st meeting with Prof J. Bradley (04.12.2012)

Initially our projects was Effective circuit model of a capacitively coupled plasma discharge. On the meeting prof Bradley suggested another project instead which was One atmosphere uniform glow discharge plasma. We are to research this type of plasma in order to give a better understanding of the OAUGDP and also contribute to prof. Bradley's current work on plasma.

Project specifications:
  • design and simulate an equivalent circuit for the glow discharge on PSpice
  • investigate the voltage and current memory effects
  • voltage breakdown effects with Zener diodes 
  • general information about the OAUGDP
Prof. Bradley also gave us guidance on the required literature. We have to find and extract information of the scientific journals of F. Massines and Zhiyu Chen who were working on this specific type of plasma, and any relevant books or articles on the OAUGDP.

Sunday 3 March 2013

Abstract

The aim of this research is to contribute to the understanding of the OAUGDP. The main gases used for such experiments are nitrogen, helium and argon. The one chosen for this project is argon as it has much lower breakdown voltage than Nitrogen and more sharply defined characteristics than Helium in terms of voltage-current ratio.An equivalent circuit of the glow discharge is designed with the PSpice software. Several simulations are carried out for the voltages at each point of the discharge equivalent circuit. The values used for the components of the circuit are calculated with the equations presented further in the blog. The glow discharge characteristics of the occurring phenomenons are described with the increasing current and voltage. Also the visual behavior of the glow discharge is presented identifying the various visible regions of the glow discharge plasma in a cathode tube. Some industrial applications of the OAUGDP are also discussed in the project along with a sustainability report on this topic.

Monday 25 February 2013

Background

Plasma - a distinct phase of matter, considered as the 4th state. It is a collection of charged particles that respond to electromagnetic fields. Since the particles in plasma are electrically charged (generally by being stripped of electrons) it is frequently described as ionized gas.
  • Plasma was identified by Sir Williams Crookes in 1879.
  • Plasma's nature of matter was identified in 1897.
  • The term "plasma" was assigned by Irving Langmuir in 1928.
  • Examples of plasma: flame, lightning, nebulae, stars, the empty vastness of space etc.





Low-pressure plasma discharges:
  • Glow discharge - non-thermal plasma generated by the application of DC or low frequency (RF below 100KHz) electric field to the gap between two metal electrodes.
  • Capacitively Coupled Plasma - generated with high frequency RF electric fields. typically 13.56 MHz. The sheaths are much less intense than the glow discharge.

Atmospheric pressure plasma discharges:
  • Dielectric Barrier Discharge (DBD) - non-thermal discharge generated by the application of high voltages across small gaps wherein a non-conducting coating prevents the transition of the plasma discharge into an arc. 
  • Capacitive Discharge - non-thermal plasma generated by the application of RF power to one powered electrode with a grounded electrode held at a small separation distance around 1 cm. Usually helium or argon are used.